English Intern
    Prof. Dr. W. A. Schenk

    Thioketenes

    Thioketene complexes are readily accessible from thiocarboxylate complexes by an acylation-elimination route [76]. This method is particularly suited for thioketenes which cannot be isolated in the free state.

     

    Molecular Structure of [CpRu(dppm)(SC(O)CH2Ph)]
    Structure of the cation of [CpRu(dppm)(eta2-S=C=CHPh)]PF6 [76]
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