English Intern
    Prof. Dr. W. A. Schenk


    Transition metal complexes of thioaldehydes have been known for quite a while. We have some time ago found a new access to this class of compounds consisting of a beta-hydride abstraction [56].

    With strongly electron-donating phosphine ligands at the ruthenium atom, rapid eta1/eta2 coordination equilibria were found [67], whereas the similar rhenium complexes exist predominantly as eta2 isomers [70, 86, 96]. The rhenium complexes are particularly suited to stabilize aliphatic thioaldehydes including those containing various functional groups in the side chain [91, 93, 96, 119].


    Structure of the cation of [CpRu(dppe)(eta1-S=CHC6H4OMe)]PF6 [67]
    Structure of the cation of [CpRe(NO)(PPh3)2(eta2-S=CHPh)]PF6 [70]

    A second method of synthesis which is also applicable to complexes of unsaturated thioaldehydes as well as thioketones is based on an acid-catalyzed condensation reaction [86, 114, 117, 123].

    Although these "stabilized" thioaldehydes are less reactive than the uncoordinated ones, they still undergo nucleophilic additions and [2+4]-cycloadditions [67, 86, 114, 123].


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