Intern
    Prof. Dr. Reinhold Tacke

    Publications 2013-2017

    44.J. A. Baus, R. Tacke, Neutral six-xoordinate bis(dithiocarbamato)-silicon(IV) complexes with an SiCl2S4 skeleton, Dalton Trans., in print (2017.) http://dx.doi.org/10.1002/ejic.201600982more ... 
    43.J. A. Baus, F. M. Mück, H. Schneider, R. Tacke, Iron(II), cobalt(II), and zinc(II) silylene complexes: reaction of the silylene [i(PrNC(NiPr2)NiPr2]Si with FeBr2, CoBr2,
    NiBe2 • MeOCH2CH2OMe, ZnCl2, and ZnBr2, Chem. Eur. J. 23, 296-303 (2017). http://dx.doi.org/10.1002/ejic.201600982more ... 
    42.J. A. Baus, J. Poater, F. M. Bickelhaupt, R. Tacke, Silylene-induced reduction of [Mn2(CO)10]: formation of a five-coordinate silicon(IV) complex with an O-bound [(OC)4Mn=Mn)CO)4]2- ligand, Eur. J. Inorg. Chem. 186-191 (2017). http://dx.doi.org/10.1002/ejic.201600982more ... 
    41.J. A. Baus, N. Laskowski, R. Tacke, A Silacyclopropene with a six-coordinate silicon atom and an SiN4C2 skeleton: synthesis and structural characterization, Eur. J. Inorg. Chem. 5182-5184 (2016). more ... 
    40.J. A. Baus, F. M. Mück, R. Bertermann, R. Tacke, Homoleptic two-coordinate
    14-electron palladium and platinum complexes with two bis(guanidinato)silylene ligands, Eur. J. Inorg. Chem. 4867-4871 (2016). more ... 
    39.F. M. Mück, J. A. Baus, C. Burschka, R. Bertermann, R. Tacke, Lewis acid/base reactions of the bis(amidinato)silylene [iPrNC(Ph)NiPr]2Si with ElPh3 (El = B, Al), Organometallics 35, 2583-2588 (2016). more ... 
    38.F. M. Mück, J. A. Baus, M. Nutz, C. Burschka, R. Bertermann, B. Förster, R. Tacke, Four-, five-, and six-coordinate silicon(IV) complexes: reactivity of the donor-stabilized silylenes [iPrNC(Ph)NiPr]2Si and [iPrNC(NiPr2)NiPr]2Si towards Me3SiN3 and PhSCH2N3, Eur. J. Inorg. Chem. 3246-3252 (2016). more ... 
    37.F. M. Mück, J. A. Baus, M. Nutz, C. Burschka, R. Bertermann, R. Tacke, SO2 activation by the bis(guanidinato)silylene [iPrNC(NiPr2)NiPr]2Si: formation of neutral six-coordinate silicon(IV) complexes with a chelating sulfito or dithionito ligand, Eur. J. Inorg. Chem. 3240-3245 (2016). more ... 
    36.F. M. Mück, J. A. Baus, C. Burschka, R. Tacke, Cationic five-coordinate bis(guanidinato)silicon(IV) complexes with SiN4El skeletons (El = S, Se): "Heterolytic activation" of S-S and Se-Se bonds, Chem. Eur. J. 22, 5830-5834 (2016). more ...
    35.F. M. Mück, J. A. Baus, A. Ulmer, C. Burschka, R. Tacke, Reactivity of the donor-stabilized guanidinatosilylene [ArNC(NMe2)NAr]Si[N(SiMe3)2] (Ar = 2,6-Diisopropylphenyl), Eur. J. Inorg. Chem. 1660-1670 (2016). more ...
    34.J. Ehbets, S. Lorenzen, C. Mahler, R. Bertermann, A. Berkefeld, J. Poater, E. Fritz-Langhals, R. Weidner, F. M. Bickelhaupt, R. Tacke, Synthesis and hydrolysis of alkoxy(aminoalkyl)diorganylsilanes of the formula type R2(RO)Si(CH2)nNH2 (R = Alkyl, n = 1-3): A systematic experimental and computational study, Eur. J. Inorg. Chem. 1641-1659 (2016). more ...
    33.M. Geyer, J. A. Baus, O. Fjellström, E. Wellner, L. Gustafsson, R. Tacke, Synthesis and pharmacological properties of silicon-sontaining GPR81 and GPR109A agonists, ChemMedChem 10, 2063-2070 (2015). more ...

    32.F. M. Mück, J. A. Baus, M. Nutz, C. Burschka, J. Poater, F. M. Bickelhaupt, R. Tacke, Reactivity of the donor-stabilized silylenes [iPrNC(Ph)NiPr]2Si and [iPrNC(NiPr2)NiPr]2Si: Activation of CO2 and CS2, Chem. Eur. J. 21, 16665-16672 (2015). more ...

    31.K. Samedov, R. West, P. W. Percival, J.-C. Brodovitch, L. Chandrasena, M. Mozafari, R. Tacke, K. Junold, C. Kobelt, P. O. Samuel, R. Azakahar, K. C. Mondal, H. W. Roesky, M. Driess, W. Wang, Free radicals of N-donor-stabilized silicon(II) compounds probed by Muon spin spectroscopy, Organometallics 34, 3532-3537 (2015). more ...

    30.  F. M. Mück, D. Kloß, J. A. Baus, C. Burschka, R. Bertermann, J. Poater, C. Fonseca Guerra, F. M. Bickelhaupt, R. Tacke, Stable four-coordinate guanidinatosilicon(IV) complexes with SiN3El skeletons (El = S, Se, Te) and Si=El double bonds, Chem. Eur. J. 21, 14011-14021 (2015). more ...

    29.R. Tacke, C. Kobelt, J. A. Baus , R.Bertermann, C. Burschka, Synthesis, structure and reactivity of a donor-stabilised silylene with a bulky bidentate benzamidinato ligand, Dalton Trans. 44, 1459-14974 (2015). more ...

    28.P. Luger, B. Dittrich, R. Tacke, Invariom based electron density studies on the C/Si analogues haloperidol/sila-haloperidol and venlafaxine/sila-venlafaxine, Org. Biomol. Chem. 13, 9093-9106 (2015). more ...

    27.M. Geyer, O. Karlsson, J. A. Baus, E. Wellner, R. Tacke, Si- and C-functional organosilicon building blocks for synthesis based on 4-silacyclohexan-1-ones containing the silicon protecting groups MOP (4-methoxyphenyl), DMOP (2,6-dimethoxyphenyl), or TMOP (2,4,6-trimethoxyphenyl), J. Org. Chem. 80, 5804-5811 (2015). more ...

    26.M. Geyer, E. Wellner, U. Jurva, S. Saloman, D. Amstrong, R. Tacke, Can silicon make an excellent drug even better? An in vitro and in vivo head-to-head comparison between loperaminde and its silicon analogue sila-loperamide, ChemMedChem 10, 911-924 (2015). more...

    25.F. M. Mück, A. Ulmer, J. A. Baus, C. Burschka, R. Tacke, Thermally stable four-coordinate silicon(IV) complexes with an Si=N double bond and an SiN3X skeleton (X = O, S, Se, Te), Eur. J. Inorg. Chem. 1860-1864 (2015). more...

    24.K. Junold, K. Sinner, J. A. Baus, C. Burschka, C. Fonseca Guerra, F. M. Bickelhaupt, R. Tacke, Reactions of the donor-stabilized silylene bis[N,N´-diisopropylbenzamidinato(–)]silicon(II) with Brønsted acids, Chem. Eur. J. 20, 16462-16466 (2014). read more...

    23.S. Dörrich, L. Gelis, S. Wolf, A. Sunderkötter, C. Mahler, E. Guschina, R. Tacke, H. Hatt, P. Kraft, Comparative analysis of the olfactory properties of  Si/Ge/Sn analogues of the lily-of-the-valley odorants lilial and bourgeonal, ChemPlusChem 79, 1747-1752 (2014). read more...

    22.S. Dörrich, C. Mahler, R. Tacke, P. Kraft, Synthesis and olfactory characterization of silicon-containing derivatives of the acyclic lily-of-the-valley odorant 5,7,7-trimethyl-4-methylideoctanal, Chemistry & Biodiversity 11, 1675-1687 (2014). more...

    21.N. Laskowski, K. Junold, C. Kupper, J. A. Baus, C. Burschka, R. Tacke, Bis[N,N'-diisopropylbenzamidinato(–)]silicon(II): Cycloaddition reactions with organic 1,3-dienes and 1,2-diketones, Organometallics 33, 6141-6148 (2014). more...

    20.K. Junold, J. A. Baus, C. Burschka, M. Finze, R. Tacke, Selective C-H bond activation of 1,2-Dicarba-closo-dodecaborane by the donor-stabilzed silylene bis[N,N’-diisopropylbenzamidinato(-)]silicon(II), Eur. J. Inorg. Chem. 5099-5102 (2014). more...

    19.K. Junold, F. M. Mück, C. Kupper, J. A. Baus, C. Burschka, R. Tacke, Activation of sulfur dioxide by bis[N,N´-diisopropylbenz- amidinato(-)]silicon(II): synthesis of neutral six-coordinate silicon(IV) complexes with chelating O,O´-sulfito or O,O´-dithionito ligands, Chem. Eur. J. 20, 12781-12785 (2014). more...

    18.S. Dörrich, A. Ulmer, C. Mahler, C. Burschka, J. A. Baus, R. Tacke, A. Chai, C. Ding, Y. Zou, G. Brunner, A. Goeke, P. Kraft, Sila-α-galbanone and analogues: synthesis and olfactory characterization of silicon-containing derivatives of the galbanum odorant α-galbanone, Eur. J. Inorg. Chem. 4394-4407 (2014). more...

    17.K. Junold, J. A. Baus, C. Burschka, C. Fonseca Guerra, F. M.  Bickelhaupt, R. Tacke, Bis[N,N’-diisopropylbenzamidinato(-)]silicon(ii): Lewis acid/base reactions with triorganylboranes, Chem. Eur. J. 20, 12411-12415 (2014). more...

    16.F. M. Mück, D. Kloss, J. A. Baus, C. Burschka, R. Tacke, Novel transition-metal (M = Cr, Mo, W, Fe) carbonyl complexes with bis(guanidinato)silicon(II) ligands, Chem. Eur. J. 20, 9620-9626 (2014). more...

    15.A. Berkefeld, C. F. Guerra, R. Bertermann, D. Troegel, J. O. Daiß, J. O. Stohrer, F. M. Bickelhaupt, R. Tacke, Silicon α-effect: A systematic experimental and computational study of the hydrolysis of Cα- and Cγ-functionalized alkoxytriorganylsilanes of the formula type ROSiMe2(CH2)nX (R = Me, Et; n = 1, 3; X = functional group), Organometallics 33, 2721-2737 (2014). more...

    14.K. Junold, M. Nutz, J. A. Baus, C. Burschka, C. F. Guerra, F. M. Bickelhaupt, R. Tacke, The donor-stabilized silylene bis[N,N´-diisopropylbenzamidinato(–)]silicon(II): synthesis, electronic structure, and reactivity, Chem. Eur. J. 20, 9319-9329 (2014). more...

    13.J. Weiß,  J. A. Baus, C. Burschka,  R. Tacke, Neutral hexacoordinate silicon(IV) complexes with a tridentate dianionic O,N,X ligand (X = O, N, S), bidentate monoanionic X,N ligand (X = O, S), and phenyl ligand: compounds with an SiO3N2C, SiSO2N2C, SiO2N3C, SiSON3C, or SiS2ON2C skeleton, Eur. J. Inorg. Chem., 2449-2455 (2014). more...

    12.M. Fischer, C. Burschka, R. Tacke, Synthesis of 4-silacyclohexan-1-ones and (4 silacyclohexan-1-yl)amines containing the silicon protecting groups MOP (4-methoxyphenyl), DMOP (2,4-dimethoxyphenyl), or TMOP (2,4,6-trimethoxyphenyl): versatile Si- and C-functional building blocks for synthesis, Organometallics 33, 1020-1029 (2014). more...

    11.J. Friedrich, S. Dörrich, A. Berkefeld, P. Kraft, R. Tacke, Synthesis and olfactory characterization of sila-methyl pamplemousse and related odorants with a 2,2,5-trimethyl-2-silahex-4-ene skeleton, Organometallics 33, 796-803 (2014). more...

    10.J. Weiß, B. Theis, J. A. Baus, C. Burschka, R. Bertermann, R. Tacke, Neutral pentacoordinate silicon(IV) complexes with a tridentate dianionic O,N,O or N,N,O ligand, an anionic PhX ligand (X = O, S, Se), and a phenyl group: synthesis and structural characterization in the solid state and in solution, Z. Allg. Anorg. Chem. 640 (2), 300-309 (2014). more...

    9.B. Förster, R. Bertemann, P. Kraft, R. Tacke, Sila-rhubafuran and derivatives: synthesis and olfactory characterization of novel silicon containing odorants, Organometallics 33, 338-346 (2014). more...

    8.J. Weiß,  K. Sinner, J. A. Baus, C. Burschka,  R. Tacke, Neutral hexacoordinate silicon(IV) complexes with a SiO4NC or SiO3N2C skeleton and neutral pentacoordinate silicon(IV) complexes containing a trianionic tetradentate O,N,O',O'' ligand, Eur. J. Inorg. Chem. 475-483 (2014). more...

    7.M. Fischer, R. Tacke, Synthesis of 4-silapiperidine building blocks with N–H groups using the Staudinger reaction, Organometallics 32, 7181–7185 (2013). more...

    6.F. M. Mück, K. Junold, J. A. Baus, C. Burschka, R. Tacke, Donor-stabilized silylenes with guanidinato ligands, Eur. J. Inorg. Chem. 5281-5825 (2013). more...

    5.K. Junold, J. Baus, C. Burschka, T. Vent-Schmidt, S. Riedel, R. Tacke, Five-coordinate silicon(II) compounds with Si–M bonds (M = Cr, Mo, W, Fe): bis[N,N´-diisopropylbenza midinato(–)]silicon(II) as a ligand in transition-metal complexes, Inorg.Chem. 52, 11593-11599 (2013). more...

    4.J. Baus, C. Burschka, R. Bertermann, C. F. Guerra, F. M. Bickelhaupt, R. Tacke, Neutral six-coordinate and cationic five-coordinate silicon(IV) complexes with two bidentate monoanionic N,S-pyridine-2-thiolato(–) ligands, Inorg. Chem. 52, 10664-10676 (2013). more ...

    3.S. Dörrich, J. B. Bauer, S. Lorenzen, C. Mahler, S. Schweeberg, C. Burschka, J. A. Baus, R. Tacke, P. Kraft, Disila-galaxolide and derivatives: synthesis and olfactory characterization of silicon-containing derivatives of the musk odorant galaxolide, Chem. Eur. J19, 11396-11408 (2013). more ...

    2.N. Laskowski, E.-M. Reis, L. Kötzner, J. A. Baus, C. Burschka, R. Tacke, Synthesis of Si-functionalized (silylmethyl)silanes and α,ω-dichlorocarbosilanes using the TMOP (2,4,6-Trimethoxyphenyl) protecting group: (TMOP)Me2SiCH2Cl and (TMOP)2MeSiCH2Cl as reagents to introduce the ClMe2SiCH2, MeOMe2SiCH2, or Cl2MeSiCH2 group by nucleophilic substitution at silicon, Organometallics 32, 3269-3278, (2013). more ...

    1.P. Luger, M. Weber, C. Hübschle, R. Tacke, Electron densities of bexarotene and disila-bexarotene from invariom application: a comparative study, Org. Biomol. Chem. 11, 2348-2354 (2013). more ...

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