Arbeitsgruppe Braunschweig

Latest Publications


Prof. Holger Braunschweig has published over 540 manuscripts since 1990, the majority of which appeared in first ranking journals such as ScienceNatureNature ChemistryAngewandte ChemieChemistry - A European Journal,...  

Latest Publications 2019/2020 

552 U. Schmidt, L. Werner, M. Arrowsmith, A. Deißenberger, A. Hermann, A. Hofmann, S. Ullrich, J. D. Mattock, A. Vargas, H. Braunschweig
Trans-selective Insertional Dihydroboration of a cis-Diborene: Synthesis of Linear sp3-sp2-sp3-Triboranes and Subsequent Cationization
Angew. Chem. 2020132, 333–337; Angew. Chem. Int. Ed. 202059, 325–329.
551 D. Prieschl, G. Bélanger-Chabot, X. Guo, M. Dietz, M. Müller, I. Krummenacher, Z. Lin, H. Braunschweig
Synthesis of Complex Boron-Nitrogen Heterocycles Comprising Borylated Triazenes and Tetrazenes Under Mild Conditions
J. Am. Chem. Soc. 2020142, 1065–1076.
550 T. E. Stennett, A. Jayaraman, T. Brückner, L. Schneider, H. Braunschweig
Hydrophosphination of boron-boron multiple bonds
Chem. Sci. 202010, 1335–1341.
549 S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Hermann, V. Paprocki, R. Drescher, I. Krummenacher, H. Braunschweig
Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling
Chem. Sci. 202010, 551–555.
548 J. T. Goettel, H. Gao, S. Dotzauer, H. Braunschweig
MeCAAC=N: A Cyclic (Alkyl)(Amino)Carbene Imino Ligand
Chem. Eur. J. 202026, 1136–1143.
547 J. Merz, M. Dietz, Y. Vonhausen, F. Wöber, A. Friedrich, D. Sieh, I. Krummenacher, H. Braunschweig, M. Moos, M. Holzapfel, C. Lambert, T. B. Marder
Synthesis, Photophysical and Electronic Properties of New Red-to-NIR Emitting Donor-Acceptor Pyrene Derivatives
Chem. Eur. J. 202026, 438–453.
546 G. Horrer, M. J. Krahfuß, K. Lubitz, I. Krummenacher, H. Braunschweig, U. Radius
N-Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbine Complexes of Titanium(IV) and Titanium(III)
Eur. J. Inorg. Chem. 2020, 281–291.
545 M. Rang, H. Braunschweig
Die Verkettung zweier Stickstoffmoleküle
Chem. unserer Zeit 202054, 8–9
544 M.-A. Légaré, M. Rang, G. Bélanger-Chabot, J. I. Schweizer, I. Krummenacher, R. Bertermann, M. Arrowsmith, M. C. Holthausen, H. Braunschweig
The reductive coupling of dinitrogen
Science 2019363, 1329–1332.
543 G. Bélanger-Chabot, H. Braunschweig
Hexahalodiborate Dianions: A New Family of Binary Boron Halides
Angew. Chem. 2019131, 14408–14412; Angew. Chem. Int. Ed. 201958, 14270–14274.
542 C. Pranckevicius, C. Herok, F. Fantuzzi, B. Engels, H. Braunschweig
Bond-Strengthening Backdonation in Aminoborylene-Stabilized Aminoborylenes: At the Intersection of Borylenes and Diborenes
Angew. Chem. 2019131, 13025–13029; Angew. Chem. Int. Ed. 201958, 12893–12897.
541 M. Dömling, M. Arrowsmith, U. Schmidt, L. Werner, A. C. Castro, J. O. C. Jiménez-Halla, R. Bertermann, J. H. Müssig, D. Prieschl, H. Braunschweig
Spontaneous trans-Selective Transfer Hydrogenation of Apolar Boron-Boron Double Bonds
Angew. Chem. 2019131, 9884–9889; Angew. Chem. Int. Ed. 201958, 9782–9786.
540 A. Hofmann, M.-A. Légaré, L. Wüst, H. Braunschweig
Heterodiatomic Multiple Bonding in Group 13: A Complex with a Boron-Alumnium π Bond Reduces CO2
Angew. Chem. 2019131, 9878–9883; Angew. Chem. Int. Ed. 201958, 9776–9781.
539 T. E. Stennett, P. Bissinger, S. Griesbeck, S. Ullrich, I. Krummenacher, M. Auth, A. Sperlich, M. Stolte, K. Radacki, C.-J. Yao, F. Würthner, A. Steffen, T. B. Marder, H. Braunschweig
Near-Infrared Quadrupolar Chromophores Combining Three-Coordinate Boron-Based Superdonor and Superacceptor Units
Angew. Chem. 2019131, 6516–6521; Angew. Chem. Int. Ed. 201958, 6449–6454.
538 J. H. Müssig, M. Thaler, R. D. Dewhurst, V. Paprocki, J. Seufert, J. D. Mattock, A. Vargas, H. Braunschweig
Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds
Angew. Chem. 2019131, 4451–4456; Angew. Chem. Int. Ed. 201958, 4405–4409.
537 A. Hofmann, C. Pranckevicius, T. Tröster, H. Braunschweig
Aluminum(I)/Boron(III) Redox Reactions
Angew. Chem. 2019131, 3664–3668; Angew. Chem. Int. Ed. 201958, 3625–3629.
536 Q. Zhao, R. D. Dewhurst, H. Braunschweig, X. Chen
A New Perspective on Borane Chemistry: The Nucleophilicity of the of the B-H Bonding Pair Electrons
Angew. Chem. 2019131, 3302–3313; Angew. Chem. Int. Ed. 201958, 3268–3278.
535 A. Deißenberger, E. Welz, R. Drescher, I. Krummenacher, R. D. Dewhurst, B. Engels, H. Braunschweig
A New Class of Neutral Boron-Based Diradicals Spanned by a Two-Carbon-Atom Bridge
Angew. Chem. 2019131, 1857–1861; Angew. Chem. Int. Ed. 201958, 1842–1846.
534 F. Lindl, S. Lin, I. Krummenacher, C. Lenczyk, A. Stoy, M. Müller, Z. Lin, H. Braunschweig
1,2,3-Diazaborinine: A BN Analog of Pyridine by Ring Expansion of a Borole with an Organic Azide
Angew. Chem. 2019131, 344–348; Angew. Chem. Int. Ed. 201958, 338–342.
533 S. K. Mellerup, Y. Cui, F. Fantuzzi, P. Schmid, J. T. Goettel, G. Bélanger-Chabot, M. Arrowsmith, I. Krummenacher, Q. Ye, V. Engel, B. Engels, H. Braunschweig
Lewis-Base Stabilization of the Parent Al(I) Hydride under Ambient Conditions
J. Am. Chem. Soc. 2019141, 16954–16960.
532 T. Brückner, T. E. Stennett, M. Heß, H. Braunschweig
Single and Double Hydroboration of B-B Triple Bonds and Convergent Routes to a Cationic Tetraborane
J. Am. Chem. Soc. 2019141, 14898–14903.
531 M.-A. Légaré, C. Pranckevicius, H. Braunschweig
Metallomimetic Chemistry of Boron
Chem. Rev. 2019119, 8231–8261.
530 J. T. Goettel, H. Braunschweig
Recent Advances in Boron-Centered Ligands and Their Transition Metal Complexes
Coord. Chem. Rev. 2019, 184–200.
529 A. Schuhmann, F. Reiß, H. Jiao, J. Rabeah, J.-E. Siewert, I. Krummenacher, H. Braunschweig, C. Hering-Junghans
A selective route to aryl-triphosphiranes and their titanocne-induced fragmentation
Chem. Sci. 201910, 7859–7867.
528 J. Merz, A. Steffen, J. Nitsch, J. Fink, C. B. Schürger, A. Friedrich, I. Krummenacher, H. Braunschweig, M. Moos, D. Mims, C. Lambert, T. B. Marder
Synthesis, photophysical and electronic properties of tetra-donor- or acceptor-aubstituted ortho-perylenes displaying four reversible oxidations or reductions
Chem. Sci. 201910, 7516–7534.
527 T. Brückner, R. D. Dewhurst, T. Dellermann, M. Müller, H. Braunschweig
Mild synthesis of diboryldiborenes by diboration of B-B triple bonds
Chem. Sci. 201910, 7375–7378.
526 M. Arrowsmith, J. I. Schweizer, M. Heinz, M. Härterich, I. Krummenacher, M. C. Holthausen, H. Braunschweig
Synthesis and Reduction Chemistry of Mixed-Lewis-Base-Stabilized Chloroborylenes
Chem. Sci. 201910, 5095–5103.
525 S. Liu, M.-A. Légaré, A. Hofmann, A. Rempel, S. Hagspiel, H. Braunschweig
Synthesis of unsymmetrical B2E2 and B2E3 heterocycles by borylene insertion into boradichalcogeniranes
Chem. Sci. 201910, 4662–4666.
524 A. Hofmann, T. Tröster, T. Kupfer, H. Braunschweig
Monomeric Cp3tAl(I): synthesis, reactivity, and the concept of valence isomerism
Chem. Sci. 201910, 3421–3428.
523 C. Lenczyk, D. K. Roy, K. Oberdorf, J. Nitsch, R. D. Dewhurst, K. Radacki, J.-F. Halet, T. B. Marder, F. M. Bickelhaupt, H. Braunschweig
Toward Transition-Metal-Templated Construction of Arylated B4 Chains by Dihydroborane Dehydrocoupling
Chem. Eur. J. 201925, 16544–16549.
522 Y. Hattori, E. Michail, A. Schmiedel, M. Moos, M. Holzapfel, I. Krummenacher, H. Braunschweig, U. Müller, J. Pflaum, C. Lambert
Luminescent Mono-, Di-, and Triradicals: Bridging Polychlorinated Triarylmethyl Radicals by Triarylamines and Triarylboranes
Chem. Eur. J. 201925, 15463–15471.
521 J. He, F. Rauch, A. Friedrich, D. Sieh, T. Ribbeck, I. Krummenacher, H. Braunschweig, M. Finze, T. B. Marder
N-Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D-π-A Compounds
Chem. Eur. J. 201925, 13777–13784.
520 T. Thiess, S. K. Mellerup, H. Braunschweig
B-B Cleavage and Ring-Expansion of a 1,4,2,3-Diazadiborinine with N-Heterocyclic Carbenes
Chem. Eur. J. 201925, 13572–13578.
519 C. Lenczyk, D. K. Roy, J. Nitsch, K. Radacki, F. Rauch, R. D. Dewhurst, F. M. Bickelhaupt, T. B. Marder, H. Braunschweig
Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes
Chem. Eur. J. 201925, 13566–13571.
518 L. Ji, S. Hahn, P. Biegger, H. Reiss, J. Han, A. Friedrich, I. Krummenacher, H. Braunschweig, M. Moos, J. Freudenberg, C. Lambert, A. Dreuw, T. B. Marder, U. H. F. Bunz
Mono- and Dianion of a Bis(benzobuta)teraazapentacene Derivative
Chem. Eur. J. 201925, 9840–9845.
517 L. Englert, A. Stoy, M. Arrowsmith, J. H. Müssig, M. Thaler, A. Deißenberger, A. Häfner, J. Böhnke, F. Hupp, J. Seufert, J. Mies, A. Damme, T. Dellermann, K. Hammond, T. Kupfer, K. Radacki, T. Thiess, H. Braunschweig
Stable Lewis Base Adducts of Tetrahalodiboranes: Synthetic Methods and Structural Diversity
Chem. Eur. J. 201925, 8612–8622.
516 C. Lenczyk, D. K. Roy, B. Ghosh, J. Schwarzmann, A. K. Phukan, H. Braunschweig
First Bis(σ)-borane Complexes of Group 6 Transition Metals: Experimental and Theoretical Studies
Chem. Eur. J. 201925, 8585–8589.
515 M. Meier, L. Ji, J. Nitsch, I. Krummenacher, A. Deißenberger, D. Auerhammer, M. Schäfer, T. B. Marder, H. Braunschweig
Preparation and Characterization of a π-Conjugated Donor-Acceptor System Containing the Strongly Electron-Accepting Tetraphenylborolyl Unit
Chem. Eur. J. 201925, 4707–4712.
514 D. Prieschl, M. Dietz, J. H. Müssig, K. Wagner, I. Krummenacher, H. Braunschweig
Pseudodiborenes: hydride-bridged diboranes(5) as two-electron reductants of chalcogens
Chem. Commun. 201955, 9781–9784.
513 A. J. Martínez-Martínez, A. R. Kennedy, V. Paprocki, F. Fantuzzi, R. D. Dewhurst, C. T. O'Hara, H. Braunschweig, R. E. Mulvey
Selective mono- and dimetallation of a group 3 sandwich complex
Chem. Commun. 201955, 9677–9680.
512 T. Brückner, M. Arrowsmith, M. Heß, K. Hammond, M. Müller, H. Braunschweig
Synthesis of fused B,N-heterocycles by alkyne cleavage, NHC ring-expansion and C-H activation at a diboryne
Chem. Commun. 201955, 6700–6703.
511 T. Ribbeck, C. Kerpen, C. Schmidle, F. Keppner, J. A. P. Sprenger, M. Arrowsmith, H. Braunschweig, N. V. Igant’ev, M. Finze
Hydroxytricyanoborate Anion: Synthetic Aspects and Structural, Chemical, and Spectroscopic Properties
Inorg. Chem. 201958, 16689–16702.
510 J. K. Schuster, D. K. Roy, C. Lenczyk, J. Mies, H. Braunschweig
New Outcomes of Beryllium Chemistry: Lewis Base Adducts for Salt Elimination Reactions
Inorg. Chem. 201958, 2652–2658.
509 J. H. Müssig, T. E. Stennett, U. Schmidt, R. D. Dewhurst, L. Mailänder, H. Braunschweig
Oxidative addition of arsenic halides to platinum(0)
Dalton Trans. 201948, 3547–3550.
508 S. Y. Ketkov, S. Y. Tzeng, E. A. Rychagova, L. V. Kalakutskaya, M. Fuss, H. Braunschweig, W.-B. Tzeng
Rydberg state mediated multiphoton ionization of (η7-C7H7)(η5-C5H5)Cr: DFT-supported experimental insights into molecular and electronic structures of excited sandwich complexes
Phys. Chem. Chem. Phys. 201921, 9665–9671.


For a full list of publications visit our Group homepage www.braunschweiggroup.de.