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Deutsch Intern
    Prof. Dr. W. A. Schenk

    Sulfines

    Sulfines

    Ruthenium-coordinated sulfines (thioaldehyde-S-oxides) were obtained by a variety of routes including oxidation of thioaldehydes, elimination reactions of sulfinate complexes, methylene transfer to an SO complex, and SO transfer to a methylene complex [109].

    These sulfine complexes are highly dynamic and exhibit both ligand rotation and hapticity change [109].