Deutsch Intern
    Arbeitsgruppe Braunschweig

    Latest Publications


    Prof. Holger Braunschweig has published over 500 manuscripts since 1990, the majority of which appeared in first ranking journals such as ScienceNatureNature ChemistryAngewandte ChemieChemistry - A European Journal,...  

    Latest Publications 2019/2020 

    547 U. Schmidt, L. Werner, M. Arrowsmith, A. Deißenberger, A. Hermann, A. Hofmann, S. Ullrich, J. D. Mattock, A. Vargas, H. Braunschweig
    Trans-selective Insertional Dihydroboration of a cis-Diborene: Synthesis of Linear sp3-sp2-sp3-Triboranes and Subsequent Cationization
    Angew. Chem. 2020132, 333–337; Angew. Chem. Int. Ed. 202059, 325–329.
    546 S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Hermann, V. Paprocki, R. Drescher, I. Krummenacher, H. Braunschweig
    Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling
    Chem. Sci. 201910, 551–555.
    545 J. Merz, M. Dietz, Y. Vonhausen, F. Wöber, A. Friedrich, D. Sieh, I. Krummenacher, H. Braunschweig, M. Moos, M. Holzapfel, C. Lambert, T. B. Marder
    Synthesis, Photophysical and Electronic Properties of New Red-to-NIR Emitting Donor-Acceptor Pyrene Derivatives
    Chem. Eur. J. 202026, 438–453.
    544 M.-A. Légaré, M. Rang, G. Bélanger-Chabot, J. I. Schweizer, I. Krummenacher, R. Bertermann, M. Arrowsmith, M. C. Holthausen, H. Braunschweig
    The reductive coupling of dinitrogen
    Science 2019363, 1329–1332.
    543 G. Bélanger-Chabot, H. Braunschweig
    Hexahalodiborate Dianions: A New Family of Binary Boron Halides
    Angew. Chem. 2019131, 14408–14412; Angew. Chem. Int. Ed. 201958, 14270–14274.
    542 C. Pranckevicius, C. Herok, F. Fantuzzi, B. Engels, H. Braunschweig
    Bond-Strengthening Backdonation in Aminoborylene-Stabilized Aminoborylenes: At the Intersection of Borylenes and Diborenes
    Angew. Chem. 2019131, 13025–13029; Angew. Chem. Int. Ed. 201958, 12893–12897.
    541 M. Dömling, M. Arrowsmith, U. Schmidt, L. Werner, A. C. Castro, J. O. C. Jiménez-Halla, R. Bertermann, J. H. Müssig, D. Prieschl, H. Braunschweig
    Spontaneous trans-Selective Transfer Hydrogenation of Apolar Boron-Boron Double Bonds
    Angew. Chem. 2019131, 9884–9889; Angew. Chem. Int. Ed. 201958, 9782–9786.
    540 A. Hofmann, M.-A. Légaré, L. Wüst, H. Braunschweig
    Heterodiatomic Multiple Bonding in Group 13: A Complex with a Boron-Alumnium π Bond Reduces CO2
    Angew. Chem. 2019131, 9878–9883; Angew. Chem. Int. Ed. 201958, 9776–9781.
    539 T. E. Stennett, P. Bissinger, S. Griesbeck, S. Ullrich, I. Krummenacher, M. Auth, A. Sperlich, M. Stolte, K. Radacki, C.-J. Yao, F. Würthner, A. Steffen, T. B. Marder, H. Braunschweig
    Near-Infrared Quadrupolar Chromophores Combining Three-Coordinate Boron-Based Superdonor and Superacceptor Units
    Angew. Chem. 2019131, 6516–6521; Angew. Chem. Int. Ed. 201958, 6449–6454.
    538 J. H. Müssig, M. Thaler, R. D. Dewhurst, V. Paprocki, J. Seufert, J. D. Mattock, A. Vargas, H. Braunschweig
    Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds
    Angew. Chem. 2019131, 4451–4456; Angew. Chem. Int. Ed. 201958, 4405–4409.
    537 A. Hofmann, C. Pranckevicius, T. Tröster, H. Braunschweig
    Aluminum(I)/Boron(III) Redox Reactions
    Angew. Chem. 2019131, 3664–3668; Angew. Chem. Int. Ed. 201958, 3625–3629.
    536 Q. Zhao, R. D. Dewhurst, H. Braunschweig, X. Chen
    A New Perspective on Borane Chemistry: The Nucleophilicity of the of the B-H Bonding Pair Electrons
    Angew. Chem. 2019131, 3302–3313; Angew. Chem. Int. Ed. 201958, 3268–3278.
    535 A. Deißenberger, E. Welz, R. Drescher, I. Krummenacher, R. D. Dewhurst, B. Engels, H. Braunschweig
    A New Class of Neutral Boron-Based Diradicals Spanned by a Two-Carbon-Atom Bridge
    Angew. Chem. 2019131, 1857–1861; Angew. Chem. Int. Ed. 201958, 1842–1846.
    534 F. Lindl, S. Lin, I. Krummenacher, C. Lenczyk, A. Stoy, M. Müller, Z. Lin, H. Braunschweig
    1,2,3-Diazaborinine: A BN Analog of Pyridine by Ring Expansion of a Borole with an Organic Azide
    Angew. Chem. 2019131, 344–348; Angew. Chem. Int. Ed. 201958, 338–342.
    533 S. K. Mellerup, Y. Cui, F. Fantuzzi, P. Schmid, J. T. Goettel, G. Bélanger-Chabot, M. Arrowsmith, I. Krummenacher, Q. Ye, V. Engel, B. Engels, H. Braunschweig
    Lewis-Base Stabilization of the Parent Al(I) Hydride under Ambient Conditions
    J. Am. Chem. Soc. 2019141, 16954–16960.
    532 T. Brückner, T. E. Stennett, M. Heß, H. Braunschweig
    Single and Double Hydroboration of B-B Triple Bonds and Convergent Routes to a Cationic Tetraborane
    J. Am. Chem. Soc. 2019141, 14898–14903.
    531 M.-A. Légaré, C. Pranckevicius, H. Braunschweig
    Metallomimetic Chemistry of Boron
    Chem. Rev. 2019119, 8231–8261.
    530 J. T. Goettel, H. Braunschweig
    Recent Advances in Boron-Centered Ligands and Their Transition Metal Complexes
    Coord. Chem. Rev. 2019, 184–200.
    529 A. Schuhmann, F. Reiß, H. Jiao, J. Rabeah, J.-E. Siewert, I. Krummenacher, H. Braunschweig, C. Hering-Junghans
    A selective route to aryl-triphosphiranes and their titanocne-induced fragmentation
    Chem. Sci. 201910, 7859–7867.
    528 J. Merz, A. Steffen, J. Nitsch, J. Fink, C. B. Schürger, A. Friedrich, I. Krummenacher, H. Braunschweig, M. Moos, D. Mims, C. Lambert, T. B. Marder
    Synthesis, photophysical and electronic properties of tetra-donor- or acceptor-aubstituted ortho-perylenes displaying four reversible oxidations or reductions
    Chem. Sci. 201910, 7516–7534.
    527 T. Brückner, R. D. Dewhurst, T. Dellermann, M. Müller, H. Braunschweig
    Mild synthesis of diboryldiborenes by diboration of B-B triple bonds
    Chem. Sci. 201910, 7375–7378.
    526 M. Arrowsmith, J. I. Schweizer, M. Heinz, M. Härterich, I. Krummenacher, M. C. Holthausen, H. Braunschweig
    Synthesis and Reduction Chemistry of Mixed-Lewis-Base-Stabilized Chloroborylenes
    Chem. Sci. 201910, 5095–5103.
    525 S. Liu, M.-A. Légaré, A. Hofmann, A. Rempel, S. Hagspiel, H. Braunschweig
    Synthesis of unsymmetrical B2E2 and B2E3 heterocycles by borylene insertion into boradichalcogeniranes
    Chem. Sci. 201910, 4662–4666.
    524 A. Hofmann, T. Tröster, T. Kupfer, H. Braunschweig
    Monomeric Cp3tAl(I): synthesis, reactivity, and the concept of valence isomerism
    Chem. Sci. 201910, 3421–3428.
    523 C. Lenczyk, D. K. Roy, K. Oberdorf, J. Nitsch, R. D. Dewhurst, K. Radacki, J.-F. Halet, T. B. Marder, F. M. Bickelhaupt, H. Braunschweig
    Toward Transition-Metal-Templated Construction of Arylated B4 Chains by Dihydroborane Dehydrocoupling
    Chem. Eur. J. 201925, 16544–16549.
    522 Y. Hattori, E. Michail, A. Schmiedel, M. Moos, M. Holzapfel, I. Krummenacher, H. Braunschweig, U. Müller, J. Pflaum, C. Lambert
    Luminescent Mono-, Di-, and Triradicals: Bridging Polychlorinated Triarylmethyl Radicals by Triarylamines and Triarylboranes
    Chem. Eur. J. 201925, 15463–15471.
    521 J. He, F. Rauch, A. Friedrich, D. Sieh, T. Ribbeck, I. Krummenacher, H. Braunschweig, M. Finze, T. B. Marder
    N-Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D-π-A Compounds
    Chem. Eur. J. 201925, 13777–13784.
    520 T. Thiess, S. K. Mellerup, H. Braunschweig
    B-B Cleavage and Ring-Expansion of a 1,4,2,3-Diazadiborinine with N-Heterocyclic Carbenes
    Chem. Eur. J. 201925, 13572–13578.
    519 C. Lenczyk, D. K. Roy, J. Nitsch, K. Radacki, F. Rauch, R. D. Dewhurst, F. M. Bickelhaupt, T. B. Marder, H. Braunschweig
    Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes
    Chem. Eur. J. 201925, 13566–13571.
    518 L. Ji, S. Hahn, P. Biegger, H. Reiss, J. Han, A. Friedrich, I. Krummenacher, H. Braunschweig, M. Moos, J. Freudenberg, C. Lambert, A. Dreuw, T. B. Marder, U. H. F. Bunz
    Mono- and Dianion of a Bis(benzobuta)teraazapentacene Derivative
    Chem. Eur. J. 201925, 9840–9845.
    517 L. Englert, A. Stoy, M. Arrowsmith, J. H. Müssig, M. Thaler, A. Deißenberger, A. Häfner, J. Böhnke, F. Hupp, J. Seufert, J. Mies, A. Damme, T. Dellermann, K. Hammond, T. Kupfer, K. Radacki, T. Thiess, H. Braunschweig
    Stable Lewis Base Adducts of Tetrahalodiboranes: Synthetic Methods and Structural Diversity
    Chem. Eur. J. 201925, 8612–8622.
    516 C. Lenczyk, D. K. Roy, B. Ghosh, J. Schwarzmann, A. K. Phukan, H. Braunschweig
    First Bis(σ)-borane Complexes of Group 6 Transition Metals: Experimental and Theoretical Studies
    Chem. Eur. J. 201925, 8585–8589.
    515 M. Meier, L. Ji, J. Nitsch, I. Krummenacher, A. Deißenberger, D. Auerhammer, M. Schäfer, T. B. Marder, H. Braunschweig
    Preparation and Characterization of a π-Conjugated Donor-Acceptor System Containing the Strongly Electron-Accepting Tetraphenylborolyl Unit
    Chem. Eur. J. 201925, 4707–4712.
    514 D. Prieschl, M. Dietz, J. H. Müssig, K. Wagner, I. Krummenacher, H. Braunschweig
    Pseudodiborenes: hydride-bridged diboranes(5) as two-electron reductants of chalcogens
    Chem. Commun. 201955, 9781–9784.
    513 A. J. Martínez-Martínez, A. R. Kennedy, V. Paprocki, F. Fantuzzi, R. D. Dewhurst, C. T. O'Hara, H. Braunschweig, R. E. Mulvey
    Selective mono- and dimetallation of a group 3 sandwich complex
    Chem. Commun. 201955, 9677–9680.
    512 T. Brückner, M. Arrowsmith, M. Heß, K. Hammond, M. Müller, H. Braunschweig
    Synthesis of fused B,N-heterocycles by alkyne cleavage, NHC ring-expansion and C-H activation at a diboryne
    Chem. Commun. 201955, 6700–6703.
    511 T. Ribbeck, C. Kerpen, C. Schmidle, F. Keppner, J. A. P. Sprenger, M. Arrowsmith, H. Braunschweig, N. V. Igant’ev, M. Finze
    Hydroxytricyanoborate Anion: Synthetic Aspects and Structural, Chemical, and Spectroscopic Properties
    Inorg. Chem. 201958, 16689–16702.
    510 J. K. Schuster, D. K. Roy, C. Lenczyk, J. Mies, H. Braunschweig
    New Outcomes of Beryllium Chemistry: Lewis Base Adducts for Salt Elimination Reactions
    Inorg. Chem. 201958, 2652–2658.
    509 J. H. Müssig, T. E. Stennett, U. Schmidt, R. D. Dewhurst, L. Mailänder, H. Braunschweig
    Oxidative addition of arsenic halides to platinum(0)
    Dalton Trans. 201948, 3547–3550.
    508 S. Y. Ketkov, S. Y. Tzeng, E. A. Rychagova, L. V. Kalakutskaya, M. Fuss, H. Braunschweig, W.-B. Tzeng
    Rydberg state mediated multiphoton ionization of (η7-C7H7)(η5-C5H5)Cr: DFT-supported experimental insights into molecular and electronic structures of excited sandwich complexes
    Phys. Chem. Chem. Phys. 201921, 9665–9671.


    For a full list of publications visit our Group homepage www.braunschweiggroup.de.