Just Published in Chemistry - A European Journal19.12.2018
Lanthanide Coordination Polymers and MOFs based on the Dicyanodihydridoborate Anion
Authors: Sven H. Zottnick, Wiebke G. Daul, Christoph Kerpen, Maik Finze, Klaus Müller-Buschbaum*
Abstract: New lanthanide cyanoborates were synthesized from anhydrous lanthanide chlorides and the acid H[BH2(CN)2] in either acetonitrile or pyridine. The obtained compounds show intense photoluminescence based on either 5d–4f transitions or 4f–4f transitions of the respective lanthanide ions.