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    Institut für Anorganische Chemie

    Just Published in Chemical Communications

    28.04.2017

    Transformation of the ionic liquid [EMIM][B(CN)4] into anionic and neutral lanthanum tetracyanoborate coordination polymers by ionothermal reactions

    Authors: Sven H. Zottnick, Maik Finze, Klaus Müller-Buschbaum*

    Abstract: The lanthanum tetracyanoborate coordination polymers [EMIM] 1[LaNO3{B(CN)4}3(H2O)3] (EMIM = 1-ethyl-3-methylimidazolium) and 1[La(NO3)2[B(CN)4](H2O)4] mark first examples of Ln-tetracyanoborates that have been obtained in ionothermal syntheses without further solvents to influence e.g. viscosity. Thereby, the ionic liquid [EMIM][B(CN)4] is fully incorporated into product formation.

    Link: pubs.rsc.org/en/Content/ArticleLanding/2017/CC/C7CC01378G

    Von: Dr. Rian Dewhurst

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